Give reactions that show the hydrohalogenation and hydration of alkynes. Write a note on the addition of hydrogen halides and water to alkynes.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Hydrohalogenation of alkynes: Alkynes undergo electrophilic addition reactions with hydrogen halides ($HCl$,$HBr$,$HI$). Two molecules of hydrogen halide add to the alkyne to form a gem-dihalide,where both halogen atoms are attached to the same carbon atom.
$(b)$ Hydration of alkynes: Hydration involves the addition of water $(H_{2}O)$ in the presence of a catalyst (e.g.,$HgSO_{4}/H_{2}SO_{4}$). The reaction proceeds via electrophilic addition. First,the electrophilic $H^{+}$ from $H_{2}O$ adds to the triple bond according to Markovnikov's rule to form a stable carbocation. Subsequently,the $OH^{-}$ ion adds to form an enol (alkenol),which then undergoes tautomerization (isomerization) to form a stable aldehyde or ketone containing the $>C=O$ group.

Explore More

Similar Questions

Which reaction converts $2$-hexyne into $trans$-$2$-hexene?

In the following reaction,$Z$ is known as: $CH \equiv CH \xrightarrow{Z} CH_3CHO$

$HC \equiv CNa + Cl - CH_2 - CH_2 - CH_2 - I \to (A)$; Major product $(A)$ is

Difficult
View Solution

Which of the following reactions is not correct?

Predict the product of the following reaction sequence:
$HC \equiv CH$ $\xrightarrow[\begin{smallmatrix} (2) \text{ excess } I-CH_2-(CH_2)_2-CH_3 \\ (3) \text{ } H^{\oplus} \end{smallmatrix}]{(1) \text{ excess } NaNH_2}$

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo